Bakierska Monika, Chojnacka Agnieszka, Świętosławski Michał, Natkański Piotr, Gajewska Marta, Rutkowska Małgorzata, Molenda Marcin
Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387 Krakow, Poland.
Academic Centre for Materials and Nanotechnology, AGH University of Science and Technology, Mickiewicza 30, 30-059 Krakow, Poland.
Materials (Basel). 2017 Nov 21;10(11):1336. doi: 10.3390/ma10111336.
In this manuscript, we describe the results of our recent studies on carbon aerogels derived from natural starches. A facile method for the fabrication of carbon aerogels is presented. Moreover, the complete analysis of the carbonization process of different starch aerogels (potato, maize, and rice) was performed using thermogravimetric studies combined with a detailed analysis of evolved decomposition products. The prepared carbon aerogels were studied in terms of their morphology and electrical properties to relate the origin of starch precursor with final properties of carbon materials. The obtained results confirmed the differences in carbon aerogels' morphology, especially in materials' specific surface areas, depending on the botanical origin of precursors. The electrical conductivity measurements suggest that carbon aerogels with the best electrical properties can be obtained from potato starch.
在本论文中,我们描述了近期对源自天然淀粉的碳气凝胶的研究结果。提出了一种制备碳气凝胶的简便方法。此外,结合对分解产物的详细分析,利用热重研究对不同淀粉气凝胶(土豆、玉米和大米)的碳化过程进行了全面分析。从淀粉前驱体的来源与碳材料最终性能的关系方面,对制备的碳气凝胶的形态和电学性质进行了研究。所得结果证实了碳气凝胶形态的差异,尤其是材料的比表面积,这取决于前驱体的植物来源。电导率测量表明,由土豆淀粉可获得电学性能最佳的碳气凝胶。