Intercalative hybridization of layered double hydroxide nanocrystals with mesoporous g-CN for enhancing visible light-induced H production efficiency.

Efficient visible light active hybrid photocatalysts for H production can be synthesized by the intercalative hybridization of Zn-Cr-layered double hydroxide (Zn-Cr-LDH) with a mesoporous g-CN lattice. Small Zn-Cr-LDH nanocrystals with a size of ∼6 nm are immobilized in the mesopores of g-CN. Beyond an optimal LDH/g-CN molar ratio of 0.3, a further increase in the LDH content leads to the surface deposition of LDH crystals on the g-CN material as well as the intercalative immobilization of LDH into its mesopores, indicating the controllability of the LDH deposition site. The Zn-Cr-LDH-g-CN nanohybrids exhibit smaller surface areas than the pristine g-CN, confirming the intercalative stabilization of Zn-Cr-LDH nanocrystals in the mesopore of g-CN. The hybridization between Zn-Cr-LDH and g-CN is effective in enhancing visible light absorptivity and also in depressing electron-hole recombination, which is attributable to an efficient electronic coupling between both the hybridized components. The present Zn-Cr-LDH-g-CN nanohybrid exhibits promising photocatalytic activities for visible light-induced H production at a rate of 155.7 μmol g h, which is much superior to that of the pristine g-CN (21.7 μmol g h). The present study underscores that the intercalative immobilization of Zn-Cr-LDH crystals in the limited space of a mesopore is quite useful in improving the visible light active photocatalyst functionality of mesoporous carbon nitride.