Department of Applied Physics, Aalto University School of Science, P.O. Box 15100, 00076, Aalto, Finland.
Top Curr Chem (Cham). 2017 Nov 27;375(6):90. doi: 10.1007/s41061-017-0178-8.
Transparent conducting films (TCFs) are critical components of many optoelectronic devices that pervade modern technology. Due to their excellent optoelectronic properties and flexibility, single-walled carbon nanotube (SWNT) films are regarded as an important alternative to doped metal oxides or brittle and expensive ceramic materials. Compared with liquid-phase processing, the dry floating catalyst chemical vapor deposition (FCCVD) method without dispersion of carbon nanotubes (CNTs) in solution is more direct and simpler. By overcoming the tradeoff between CNT length and solubility during film fabrication, the dry FCCVD method enables production of films that contain longer CNTs and offer excellent optoelectronic properties. This review focuses on fabrication of SWNT films using the dry FCCVD method, covering SWNT synthesis, thin-film fabrication and performance regulation, the morphology of SWNTs and bundles, transparency and conductivity characteristics, random bundle films, patterned films, individual CNT networks, and various applications, especially as TCFs in touch displays. Films based on SWNTs produced by the dry FCCVD method are already commercially available for application in touch display devices. Further research on the dry FCCVD method could advance development of not only industrial applications of CNTs but also the fundamental science of related nanostructured materials and nanodevices.
透明导电薄膜(TCFs)是许多现代技术中光电设备的关键组成部分。由于其优异的光电性能和柔韧性,单壁碳纳米管(SWNT)薄膜被认为是掺杂金属氧化物或脆性和昂贵的陶瓷材料的重要替代品。与液相处理相比,不将碳纳米管(CNTs)分散在溶液中的干法浮动催化剂化学气相沉积(FCCVD)方法更加直接和简单。通过克服薄膜制造过程中 CNT 长度和溶解度之间的权衡,干法 FCCVD 方法能够生产出含有更长 CNT 且具有优异光电性能的薄膜。本综述重点介绍了使用干法 FCCVD 方法制备 SWNT 薄膜,涵盖了 SWNT 的合成、薄膜的制备和性能调节、SWNT 和束的形态、透明度和导电性特征、随机束薄膜、图案化薄膜、单个 CNT 网络以及各种应用,特别是作为触摸显示器中的 TCF。干法 FCCVD 方法制备的基于 SWNT 的薄膜已经可用于触摸显示设备的商业应用。对干法 FCCVD 方法的进一步研究不仅可以推动 CNT 的工业应用的发展,还可以推动相关纳米结构材料和纳米器件的基础科学的发展。