Krupp-Chair of General and Inorganic Chemistry, Saarland University, 6615, Saarbrücken, Germany.
Chemistry. 2018 May 11;24(27):6866-6885. doi: 10.1002/chem.201704090. Epub 2018 Feb 14.
Functionalized disilenes are valuable auxiliary tools in preparative chemistry. In the following review the various synthetic potential of disilenes as precursors is presented. Upon consumption of the Si=Si unit in disilenes, cyclic, polycyclic and cluster-like arrangements are obtainable.
功能化二硅烯是制备化学中的有价值的辅助工具。在以下综述中,介绍了二硅烯作为前体的各种合成潜力。二硅烯中的 Si=Si 单元消耗后,可获得环状、多环和类簇的排列。