Wu Yi-Peng, Yang Bo, Tian Jia, Yu Shang-Bo, Wang Hui, Zhang Dan-Wei, Liu Yi, Li Zhan-Ting
Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Centre of Chemistry for Energy Materials (iChEM), Fudan University, Shanghai 200433, China.
Chem Commun (Camb). 2017 Dec 14;53(100):13367-13370. doi: 10.1039/c7cc08824h.
We present the postmodification of a diamondoid 3D supramolecular organic framework (SOF) to append [Ru(BPY)] groups through the formation of a hydrazone bond. The resulting SOF works as an efficient recyclable heterogeneous catalyst for visible-light-induced reduction of aromatic azides to amines.