Octahedral-Like CuO/InO Mesocages with Double-Shell Architectures: Rational Preparation and Application in Hydrogen Sulfide Detection.

This contribution describes a facile strategy for constructing octahedral-like CuO/InO mesocages with double-shell architectures. The synthetic method included first preparation of unifrom CuO as an ideal self-sacrificial template and then decoration by a InO outer layer through room-temperature CuO-engaged redox etching reaction combined with subsequent annealing process. Various characterization techniques manifested that InO nanoparticles were uniformly grown on the surface of CuO mesocages, resulting in a well-defined double-shelled heterostructure. When evaluated as a novel sensing material for hydrogen sulfide (HS) detection, the resultant octahedral-like CuO/InO heterostructures exhibited obviously enhanced sensing response, lower operating temperature as well as faster response/recover speed during the dynamic measurement compared to the pristine CuO particles, which is likely related to the high-level of adsorbed oxygen concentration, resistance modulation effect, and unique microstructure of as-prepared CuO/InO heterostructure.