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向列型液晶与CoFeO铁磁纳米颗粒在磁场中混合时的动态行为。

Dynamic behavior of a nematic liquid crystal mixed with CoFeO ferromagnetic nanoparticles in a magnetic field.

作者信息

Petrescu Emil, Cirtoaje Cristina, Stan Cristina

机构信息

University Politehnica of Bucharest, Department of Physics, Splaiul Independenţei 313, 060042, Bucharest, Romania.

出版信息

Beilstein J Nanotechnol. 2017 Nov 22;8:2467-2473. doi: 10.3762/bjnano.8.246. eCollection 2017.

Abstract

The dynamic behavior of a mixture of 4-cyano-4'-pentylbiphenyl (5CB) with 1% CoFeO nanoparticles was analyzed. Experimental data indicate a high stability of the nematic director in the mixture compared to a reference 5CB sample in the magnetic field. The ferrite nanoparticles agglomerate forming long chains as observed in polarized microscopy images. These chains have a very high influence on the magneto-optic effect of the cell. When the magnetic field is applied on the mixture, the chains tend to align with the field direction but, due to their large size, they remain oriented obliquely between the support plates. Thus, the nematic molecules anchored on their surface can not reorient with the field and only a small distortion angle of the liquid crystal molecular director is observed. A comparison with a previously developed theoretical model confirms this small deviation.

摘要

分析了含有1% CoFeO纳米颗粒的4-氰基-4'-戊基联苯(5CB)混合物的动态行为。实验数据表明,与磁场中的参考5CB样品相比,混合物中向列型指向矢具有较高的稳定性。如偏光显微镜图像所示,铁氧体纳米颗粒团聚形成长链。这些链对液晶盒的磁光效应有很大影响。当对混合物施加磁场时,链倾向于沿磁场方向排列,但由于其尺寸较大,它们在支撑板之间保持倾斜取向。因此,锚定在其表面的向列型分子无法随磁场重新取向,仅观察到液晶分子指向矢的小畸变角。与先前开发的理论模型进行比较证实了这种小偏差。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d168/5704774/df2647ed1b0e/Beilstein_J_Nanotechnol-08-2467-g002.jpg

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