Collivignarelli Maria Cristina, Abbà Alessandro, Bertanza Giorgio, Barbieri Giacomo
Department of Civil and Architectural Engineering, University of Pavia, via Ferrata 1, 27100 Pavia, Italy.
Department of Civil, Environmental, Architectural Engineering, and Mathematics, University of Brescia, via Branze 43, 25123 Brescia, Italy E-mail:
Water Sci Technol. 2017 Dec;76(11-12):3236-3245. doi: 10.2166/wst.2017.492.
In the present work, the thermophilic aerobic membrane reactor technology was studied for the treatment of high strength aqueous wastes mainly containing dyes, surfactants and solvents. The thermophilic biomass resilience and the process stability under critical conditions (such as rapid rise of the mixed liquor pH, oxygen supply interruption, etc.) were also evaluated. The experimental work was carried out with the use of a pilot plant at semi-industrial scale, which was managed throughout for 14 months; the operation temperature was 49 °C and the organic loading rate was increased from 3 to 12 kg m d. Critical conditions, especially the interruption of oxygen supply, affected the pilot plant performance but did not cause a complete system break down. After the temporary reduction of process performance, also proven by the decrease in the oxygen consumption, the normal working conditions were restored. Moreover, the longer non-aerated phase involved a significant reduction (40%) of volatile suspended solids concentration in the biological reactor and the increase of 30% in foaming power; nevertheless, once the oxygen supply was reactivated, optimal conditions were rapidly restored. Therefore, the study showed the high resilience of the thermophilic biomass, which was able to recover full functionality after critical events.
在本研究中,对嗜热好氧膜生物反应器技术处理主要含有染料、表面活性剂和溶剂的高浓度废水进行了研究。还评估了嗜热生物质的恢复能力以及在临界条件下(如混合液pH值迅速升高、氧气供应中断等)的工艺稳定性。实验工作使用了半工业规模的中试装置进行,该装置连续运行了14个月;运行温度为49℃,有机负荷率从3 kg/m³·d提高到12 kg/m³·d。临界条件,尤其是氧气供应中断,影响了中试装置的性能,但并未导致系统完全崩溃。在工艺性能暂时下降(这也通过耗氧量的降低得到证实)之后,恢复了正常工作条件。此外,较长的非曝气阶段使生物反应器中挥发性悬浮固体浓度显著降低(40%),发泡能力增加了30%;然而,一旦重新恢复氧气供应,很快就恢复了最佳条件。因此,该研究表明嗜热生物质具有很高的恢复能力,能够在临界事件后恢复全部功能。