Ishimoto Kango, Tajima Tomoyuki, Miyake Hideaki, Yamagami Masahiro, Kurashige Wataru, Negishi Yuichi, Takaguchi Yutaka
Graduate School of Environmental and Life Science, Okayama University, 3-1-1 Tsushima-Naka, Kita-ku, Okayama 700-8530, Japan.
Chem Commun (Camb). 2018 Jan 4;54(4):393-396. doi: 10.1039/c7cc07194a.
To observe a clear-cut example of the formation of mobile carriers from excitons on semiconducting single-walled carbon nanotubes (s-SWCNTs) surrounded by a medium with a high dielectric constant, water-dispersible s-SWCNT nanocomposites were fabricated by physical modifications using poly(amidoamine) dendrimers that contain an aliphatic core. The evolution of H from water using these s-SWCNT/dendrimer nanocomposites as photosensitizers under irradiation with visible light demonstrated a photo-induced electron transfer from the s-SWCNTs to the co-catalysts.
为了观察在被高介电常数介质包围的半导体单壁碳纳米管（s-SWCNT）上由激子形成移动载流子的一个清晰例子，通过使用含有脂肪族核的聚（酰胺胺）树枝状大分子进行物理改性，制备了水分散性s-SWCNT纳米复合材料。在可见光照射下，使用这些s-SWCNT/树枝状大分子纳米复合材料作为光敏剂时，水中氢的演变表明了从s-SWCNT到助催化剂的光诱导电子转移。
