Elsayed Moussa M, Attenberger B, Peresypkina E V, Scheer M
Institut für Anorganische Chemie der Universität Regensburg, 93040 Regensburg, Germany.
Nikolaev Institute of Inorganic Chemistry, Siberian Division of RAS, Acad. Lavrentyev prosp. 3, 630090 Novosibirsk, Russia and Novosibirsk State University, ul. Pirogova, 2, 630090 Novosibirsk, Russia.
Dalton Trans. 2018 Jan 23;47(4):1014-1017. doi: 10.1039/c7dt04286h.
The reaction of the P ligand complex [CpFe(η-P)] (1: Cp = η-CMe) with CuCl in the presence of 4,4'-bipyridine or 1,2-di(4-pyridyl)ethylene leads to the formation of three unprecedented neutral 2D organometallic-organic hybrid networks, the constitutional isomers [CuCl{CpFe(μ,η-P)}(μ,η-CHN)] (2 and 3) and the coordination polymer [(CuCl){CpFe(μ,η-P)}(μ,η-CHN)] (4) with isomeric square (2 and 3) and honeycomb (4) layer topologies.
在4,4'-联吡啶或1,2-二(4-吡啶基)乙烯存在下，P配体配合物[CpFe(η-P)]（1：Cp = η-CMe）与CuCl反应，生成了三种前所未有的中性二维有机金属-有机杂化网络，即结构异构体[CuCl{CpFe(μ,η-P)}(μ,η-CHN)]（2和3）以及具有异构方形（2和3）和蜂窝状（4）层拓扑结构的配位聚合物[(CuCl){CpFe(μ,η-P)}(μ,η-CHN)]（4）。
