Wang Siping, Liu Jie, Zhao Hongmei, Guo Zhifen, Xing Hongzhu, Gao Yuan
Provincial Key Laboratory of Advanced Energy Materials, College of Chemistry, Northeast Normal University , Renmin Street 5268, Changchun 130024, China.
State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University , Qianjin Street 2699, Changchun 130012, China.
Inorg Chem. 2018 Jan 16;57(2):541-544. doi: 10.1021/acs.inorgchem.7b02464. Epub 2017 Dec 27.
A new electrically conductive coordination polymer is synthesized using anthracene-incorporated organic ligand. The compound exhibits a band-like structure and long-range π-π stacking of ligand. Interestingly, the fabricated chemiresisitor using this coordination polymer shows selective sensing behavior for volatile amine detection with characteristics of quick response, good reproducibility, and room-temperature operation. This study not only presents a rare example of electrically conductive coordination polymer but also illustrates the useful application of coordination polymer for chemiresistor.
一种使用含蒽有机配体合成的新型导电配位聚合物。该化合物呈现出带状结构和配体的长程π-π堆积。有趣的是，使用这种配位聚合物制造的化学电阻器对挥发性胺检测表现出选择性传感行为，具有响应快、重现性好和室温操作的特点。这项研究不仅展示了导电配位聚合物的一个罕见例子，还说明了配位聚合物在化学电阻器中的有用应用。
