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PET 纳米多孔发光纤维的形貌与性能:吸油性和荧光指示功能。

Morphologies and Properties of PET Nano Porous Luminescence Fiber: Oil Absorption and Fluorescence-Indicating Functions.

机构信息

Tianjin Key Laboratory of Advanced Fibers and Energy Storage, Tianjin Polytechnic University , 399 Bin Shui West Road, 300387 Tianjin, P.R. China.

State Key laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences , 100080 Beijing, P.R. China.

出版信息

ACS Appl Mater Interfaces. 2018 Jan 24;10(3):2828-2836. doi: 10.1021/acsami.7b16655. Epub 2018 Jan 10.

DOI:10.1021/acsami.7b16655
PMID:29294290
Abstract

A polyethylene terephthalate nano porous luminescence fiber (PNPLF) was prepared through electrospun technology. The SEM and TEM images show that the surfaces of the fibers are covered with pores. The diameter of the fiber is 250-500 nm, and the diameter of the pores is 20-180 nm. The water and oil contact angles of PNPLF are 135° and 27°, respectively. The oil absorption value of the as-prepared PNPLF achieves 135 g/g and has a good oil absorption function. The as-prepared PNPLF has good luminescence properties and fluorescent-indicating function. Even trace amounts of oil can also cause obvious change of fluorescence intensity of PNPLF which has a good stability from 20 °C to 70 °C. The breaking stress of yarn of PNPLF reaches 117cN. Furthermore, the good mechanical properties and thermal properties of PNPLF provide important basic conditions for their wide applications.

摘要

一种聚对苯二甲酸乙二醇酯纳米多孔发光纤维(PNPLF)通过静电纺丝技术制备。SEM 和 TEM 图像显示,纤维表面覆盖有孔。纤维的直径为 250-500nm,孔的直径为 20-180nm。PNPLF 的水和油接触角分别为 135°和 27°。所制备的 PNPLF 的吸油值达到 135g/g,具有良好的吸油功能。所制备的 PNPLF 具有良好的发光性能和荧光指示功能。即使是微量的油也能引起 PNPLF 荧光强度的明显变化,其在 20°C 至 70°C 之间具有良好的稳定性。PNPLF 纱线的断裂应力达到 117cN。此外,PNPLF 的良好机械性能和热性能为其广泛应用提供了重要的基础条件。

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