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嵌入形状记忆合金纤维及形状记忆合金纤维表面改性对玄武岩纤维增强塑料复合层压板力学性能的影响

Influence of Embedding SMA Fibres and SMA Fibre Surface Modification on the Mechanical Performance of BFRP Composite Laminates.

作者信息

Liu Yanfei, Wang Zhenqing, Li Hao, Sun Min, Wang Fangxin, Chen Bingjie

机构信息

College of Aerospace and Civil Engineering, Harbin Engineering University, Harbin 150001, China.

School of Mechanical Engineering, University of Leeds, Leeds LS2 9JT, UK.

出版信息

Materials (Basel). 2018 Jan 4;11(1):70. doi: 10.3390/ma11010070.

Abstract

In this paper, a new shape memory alloy (SMA) hybrid basalt fibre reinforced polymer (BFRP) composite laminate was fabricated and a new surface modification method with both silane coupling agent KH550 and Al₂O₃ nanoparticles was conducted to enhance the interface performance. The mechanical performance of BFRP composite laminates with and without SMA fibres and the influence of SMA surface modification were studied in this paper. Different SMA fibre surface treatment methods, including etching with both H₂SO₄ and NaOH, modification with the silane coupling agent KH550 and new modification method with both KH550 and Al₂O₃ nanoparticles, were conducted to enhance the bonding between the SMA fibres and polymer matrix. Scanning electron microscopy (SEM) was used to observe the micromorphology of the SMA fibre surfaces exposed to different treatments and the damage morphology of composite laminates. The mechanical performance of the composites was investigated with tensile, three-point bending and low-velocity impact tests to study the influence of embedded SMA fibres and the different surface modifications of the SMA fibres. The results demonstrated that the embedded Ni-Ti SMA fibres can significantly enhance the mechanical performance of BFRP composite laminates. SMA fibres modified with both the silane coupling agent KH550 and Al₂O₃ nanoparticles illustrate the best mechanical performance among all samples.

摘要

本文制备了一种新型形状记忆合金(SMA)混杂玄武岩纤维增强聚合物(BFRP)复合层合板,并采用硅烷偶联剂KH550和Al₂O₃纳米颗粒进行了一种新的表面改性方法,以提高界面性能。本文研究了含和不含SMA纤维的BFRP复合层合板的力学性能以及SMA表面改性的影响。采用了不同的SMA纤维表面处理方法,包括用H₂SO₄和NaOH蚀刻、用硅烷偶联剂KH550改性以及用KH550和Al₂O₃纳米颗粒的新改性方法,以增强SMA纤维与聚合物基体之间的粘结。利用扫描电子显微镜(SEM)观察了经不同处理的SMA纤维表面的微观形貌以及复合层合板的损伤形貌。通过拉伸、三点弯曲和低速冲击试验研究了复合材料的力学性能,以研究嵌入的SMA纤维和SMA纤维不同表面改性的影响。结果表明,嵌入的Ni-Ti SMA纤维可显著提高BFRP复合层合板的力学性能。用硅烷偶联剂KH550和Al₂O₃纳米颗粒改性的SMA纤维在所有样品中表现出最佳的力学性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ebb3/5793568/b56299a617ec/materials-11-00070-g001.jpg

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