具有三苯乙烯三聚体大环的多孔穿插分子笼，对空气中的 CO 和 TNT 蒸气表现出高选择性吸附。
Porous Interdigitation Molecular Cage from Tetraphenylethylene Trimeric Macrocycles That Showed Highly Selective Adsorption of CO and TNT Vapor in Air.
机构信息
Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology , Wuhan 430074, China.
College of Life Science and Technology, Huazhong University of Science and Technology , Wuhan 430074, China.
出版信息
Org Lett. 2018 Jan 19;20(2):321-324. doi: 10.1021/acs.orglett.7b03483. Epub 2018 Jan 9.
A new [3 + 3] trimeric macrocycle, based on tetraphenylethylene having an aggregation-induced emission effect, could form a interdigitation molecular cage with a big void by host-guest interactions. The cage could accommodate two TNT molecules and detect TNT at the 1.7 fg level per mL of air. Moreover, the cage could give permanent pores that had a BET surface area of 347 m/g and could adsorb 7.8 wt % CO with high CO/N selectivity up to 32 (273 K, 1 bar).
一种新型的[3+3]三聚体大环，基于具有聚集诱导发光效应的四苯乙烯，通过主客体相互作用可以形成具有大空腔的交错分子笼。该笼可以容纳两个 TNT 分子，并在每毫升空气中检测到 1.7 fg 级别的 TNT。此外，该笼可以提供具有 347 m/g BET 表面积的永久孔，并可以在 273 K 和 1 巴的条件下吸附 7.8wt%的 CO，具有高达 32 的高 CO/N 选择性。
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