Jašíková Lucie, Roithová Jana
Department of Organic Chemistry, Faculty of Science, Charles University, Hlavova 2030, Prague 2, 128 43, Czech Republic.
Chemistry. 2018 Mar 7;24(14):3374-3390. doi: 10.1002/chem.201705692. Epub 2018 Feb 13.
Infrared multiphoton dissociation (IRMPD) spectroscopy is commonly used to determine the structure of isolated, mass-selected ions in the gas phase. This method has been widely used since it became available at free-electron laser (FEL) user facilities. Thus, in this Minireview, we examine the use of IRMPD/FEL spectroscopy for investigating ions derived from small molecules, metal complexes, organometallic compounds and biorelevant ions. Furthermore, we outline new applications of IRMPD spectroscopy to study biomolecules.
红外多光子解离（IRMPD）光谱法通常用于确定气相中分离的、经质量选择的离子的结构。自该方法在自由电子激光（FEL）用户设施中可用以来，它已被广泛使用。因此，在本综述中，我们研究了IRMPD/FEL光谱法在研究源自小分子、金属配合物、有机金属化合物和生物相关离子方面的应用。此外，我们概述了IRMPD光谱法在研究生物分子方面的新应用。
