抗肿瘤药物NAMI-Pyr的二氮烯衍生物钌（III）配合物Na[反式-RuCl4（DMSO）（PyrDiaz）]的合成与X射线结构分析
Synthesis and X-ray Structural Analysis of the Ruthenium(III) Complex Na[trans-RuCl4(DMSO) (PyrDiaz)], the Diazene Derivative of Antitumor NAMI-Pyr.
作者信息
Vajs Jure, Pevec Andrej, Gazvoda Martin, Urankar Damijana, Goreshnik Evgeny, Polanc Slovenko, Košmrlj Janez
出版信息
Acta Chim Slov. 2017 Dec;64(4):763-770. doi: 10.17344/acsi.2017.3844.
Novel tetrachloridoruthenium(III) complex Na[trans-RuCl4(DMSO)(PyrDiaz)] (3) with pyridine-tethered diazenedicarboxamide PyrDiaz ligand (PyrDiaz = N1-(4-isopropylphenyl)-N2-(pyridin-2-ylmethyl)diazene-1,2-dicarboxamide) was synthesized by direct coupling of PyrDiaz with sodium trans-bis(dimethyl sulfoxide)tetrachloridoruthenate(III) (Na-[trans-Ru(DMSO)2Cl4]). Compound 3 is the analogue of the antimetastatic Ru(III) complex NAMI-A and NAMI-Pyr. Single crystal X.
新型四氯钌（III）配合物Na[反式-RuCl4（DMSO）（PyrDiaz）]（3），其带有吡啶连接的重氮二甲酰胺配体PyrDiaz（PyrDiaz = N1-（4-异丙基苯基）-N2-（吡啶-2-基甲基）二氮烯-1,2-二甲酰胺），是通过PyrDiaz与反式双（二甲基亚砜）四氯钌（III）酸钠（Na-[反式-Ru（DMSO）2Cl4]）直接偶联合成的。化合物3是抗转移Ru（III）配合物NAMI-A和NAMI-Pyr的类似物。单晶X.
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