Synthesis of functionalized helical BN-benzo[c]phenanthrenes.
作者信息
Abengózar Alberto, García-García Patricia, Sucunza David, Pérez-Redondo Adrián, Vaquero Juan J
机构信息
Departamento de Química Orgánica y Química Inorgánica, Instituto de Investigación Química "Andrés M. del Río" (IQAR), Universidad de Alcalá, 28805-Alcalá de Henares, Madrid, Spain.
出版信息
Chem Commun (Camb). 2018 Mar 6;54(20):2467-2470. doi: 10.1039/c7cc09264d.
PMID:29319090
Abstract
A novel parent BN-benzo[c]phenanthrene, with helical chirality and remarkable structural features, has been easily obtained in three steps with a global yield of 55%. Moreover, Cl-substituted derivatives have been prepared and these have served as useful starting materials for the development of palladium-catalyzed cross-coupling reactions.
摘要
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