[铜（I）（含吡啶配体）]催化的 2-乙烯基吲哚区域和立体选择性合成 2-乙烯基环丙[b]吲哚啉。
[Copper(I)(Pyridine-Containing Ligand)] Catalyzed Regio- and Steroselective Synthesis of 2-Vinylcyclopropa[b]indolines from 2-Vinylindoles.
机构信息
Dipartimento di Scienze Farmaceutiche-Sezione di Chimica Generale e Organica "A. Marchesini", Università degli Studi di Milano , Via Venezian 21, 20133 Milano, Italy.
Dipartimento di Chimica, Università degli Studi di Milano , Via Golgi 19, 20133, Milano, Italy.
出版信息
Org Lett. 2018 Jan 19;20(2):405-408. doi: 10.1021/acs.orglett.7b03704. Epub 2018 Jan 10.
PMID:29319320
Abstract
A [copper(I)pyridine-containing ligand]-catalyzed reaction between 2-vinylindoles and diazo esters is described. The reaction allows for the synthesis of a series of 2-vinylcyclopropa[b]indolines with excellent levels of regio- and sterocontrol under mild conditions.
摘要
一种[含铜（I）吡啶的配体]催化的 2-乙烯基吲哚与重氮酯的反应被描述。该反应在温和条件下能够以优异的区域和立体选择性合成一系列 2-乙烯基环丙[b]吲哚啉。
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