由第1族钳形配合物介导的二甲胺硼烷脱氢反应。
Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes.
作者信息
Nolla-Saltiel Roberto, Geer Ana M, Lewis William, Blake Alexander J, Kays Deborah L
机构信息
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK.
出版信息
Chem Commun (Camb). 2018 Feb 15;54(15):1825-1828. doi: 10.1039/c7cc08385h.
PMID:29322123
Abstract
Group 1 salts containing carbazolido NNN pincer ligands are precatalysts for the dehydrogenation of MeNH·BH. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation.
摘要
第1组含咔唑基NNN钳形配体的盐是MeNH·BH脱氢反应的预催化剂。核磁共振监测和扩散有序光谱研究表明，该反应对金属和溶剂有很大依赖性，在某些情况下可选择性地生成与氢气释放相符的脱氢产物。
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