喹啉对醌与金属：配位辅助形成喹啉邻醌
Quinoline-para-quinones and metals: coordination-assisted formation of quinoline-ortho-quinones.
作者信息
Kubanik Mario, Lam Nelson Y S, Holtkamp Hannah U, Söhnel Tilo, Anderson Robert F, Jamieson Stephen M F, Hartinger Christian G
机构信息
School of Chemical Sciences, University of Auckland, Private Bag 92019, Auckland 1142, New Zealand.
出版信息
Chem Commun (Camb). 2018 Jan 23;54(8):992-995. doi: 10.1039/c7cc09478g.
PMID:29322135
Abstract
The reaction of the para-quinone 6,7-dichloroquinoline-5,8-dione with various transition metal dimers led to the unexpected formation of quinoline-ortho-quinone metal complexes. Systematic variation of the reaction conditions helped identify the solvent as the source of the carbonyl oxygen.
摘要
对醌6,7-二氯喹啉-5,8-二酮与各种过渡金属二聚体的反应导致了意外形成喹啉-邻醌金属配合物。反应条件的系统变化有助于确定溶剂是羰基氧的来源。
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