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利用高光谱红外成像显微光谱法对萨特磨坊陨石颗粒中的碳酸盐进行研究。

Investigation of carbonates in the Sutter's Mill meteorite grains with hyperspectral infrared imaging micro-spectroscopy.

作者信息

Yesiltas Mehmet

机构信息

Faculty of Aeronautics and Space Sciences, Kirklareli University, Kirklareli 39000, Turkey.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2018 Apr 5;194:92-101. doi: 10.1016/j.saa.2018.01.021. Epub 2018 Jan 6.

Abstract

Synchrotron-based high spatial resolution hyperspectral infrared imaging technique provides thousands of infrared spectra with high resolution, thus allowing us to acquire detailed spatial maps of chemical molecular structures for many grains in short times. Utilizing this technique, thousands of infrared spectra were analyzed at once instead of inspecting each spectrum separately. Sutter's Mill meteorite is a unique carbonaceous type meteorite with highly heterogeneous chemical composition. Multiple grains from the Sutter's Mill meteorite have been studied using this technique and the presence of both hydrous and anhydrous silicate minerals have been observed. It is observed that the carbonate mineralogy varies from simple to more complex carbonates even within a few microns in the meteorite grains. These variations, the type and distribution of calcite-like vs. dolomite-like carbonates are presented by means of hyperspectral FTIR imaging spectroscopy with high resolution. Various scenarios for the formation of different carbonate compositions in the Sutter's Mill parent body are discussed.

摘要

基于同步加速器的高空间分辨率高光谱红外成像技术可提供数千个高分辨率红外光谱,从而使我们能够在短时间内获取许多颗粒化学分子结构的详细空间图谱。利用该技术,可一次性分析数千个红外光谱,而无需分别检查每个光谱。萨特磨坊陨石是一种独特的碳质陨石,其化学成分高度不均一。已使用该技术对来自萨特磨坊陨石的多个颗粒进行了研究,并观察到了含水和无水硅酸盐矿物的存在。据观察,即使在陨石颗粒内几微米的范围内,碳酸盐矿物学也从简单碳酸盐变化为更复杂的碳酸盐。通过高分辨率的高光谱傅里叶变换红外成像光谱法展示了这些变化,即方解石状与白云石状碳酸盐的类型和分布。讨论了萨特磨坊母体中不同碳酸盐成分形成的各种情况。

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