Satoh H, Nakabayashi N, Masuhara E
Shika Rikogaku Zasshi. 1978 Oct;19(48):217-26.
Effect of several cross-linking agents added to MMA on the mechanical properties of self-cured fluid resins was studied. The cross-linking agents were 2,2-bis (4-methacryloxyethoxyphenyl) propane, trimethylolpropane trimethacrylate, neopentylglycol dimethacrylate, hexamethyleneglycol dimethacrylate and 1,2-polybutadiene. Their concentrations in MMA were 1,3,5 and 10 wt%. Measured mechanical properties were Brinell hardness, tensile strength, impact strength and transverse strength. The best composition was 5% neopentylglycol dimethacrylate in MMA among studied samples. Microscopic observation of the surface after tensile test suggested that diffusibility of cross-linking agents into PMMA powder affected the mechanical properties. Mechanical properties of both matrix and powder, and their adhesion at the interface had influence upon the mechanical properties of resins processed by powder-liquid method.
研究了添加到甲基丙烯酸甲酯(MMA)中的几种交联剂对自固化流体树脂力学性能的影响。交联剂为2,2-双(4-甲基丙烯酰氧基乙氧基苯基)丙烷、三羟甲基丙烷三甲基丙烯酸酯、新戊二醇二甲基丙烯酸酯、六亚甲基二醇二甲基丙烯酸酯和1,2-聚丁二烯。它们在MMA中的浓度分别为1%、3%、5%和10%(重量)。所测量的力学性能包括布氏硬度、拉伸强度、冲击强度和横向强度。在所研究的样品中,最佳配方是MMA中含有5%的新戊二醇二甲基丙烯酸酯。拉伸试验后表面的微观观察表明,交联剂向聚甲基丙烯酸甲酯(PMMA)粉末中的扩散性影响了力学性能。基体和粉末的力学性能以及它们在界面处的粘附力对通过粉液法加工的树脂的力学性能有影响。