Nagata K, Suzuki S, Nakabayashi N, Masuhara E
Shika Rikogaku Zasshi. 1979 Jan;20(49):8-13.
Elimination of PMMA powder to prepare better hard crown and bridge resin had been pointed out by the authors even though polyfunctional methacrylates were used. Application of hydrophobic coloidal silica instead of PMMA pearl with triethyleneglycol dimethacrylate and Bis-GMA was studied. Polyermization was carried out in the hot air stream at 120 degrees approximately 130 degrees C or in a pressure vessel at 4.5 kg/cm2 gauge, 100 degrees C. Mechanical properties, brinell hardness, compressive strength, an amount of water sorption, comparative average abrasion loss depth with those of PMMA, were measured. They were improved very much by this new system.
作者指出,即使使用了多官能甲基丙烯酸酯,去除聚甲基丙烯酸甲酯(PMMA)粉末以制备更好的硬质冠桥树脂也是有必要的。研究了用疏水性胶体二氧化硅代替聚甲基丙烯酸甲酯微珠,并与三乙二醇二甲基丙烯酸酯和双酚A - 甲基丙烯酸缩水甘油酯(Bis - GMA)一起使用。聚合反应在约120℃至130℃的热气流中或在压力为4.5 kg/cm²表压、温度为100℃的压力容器中进行。测量了其机械性能、布氏硬度、抗压强度、吸水率以及与聚甲基丙烯酸甲酯相比的平均磨损损失深度。通过这种新体系,这些性能有了很大改善。