单核锰（III）-氢过氧配合物：通过活化氧气合成及其在亲电和亲核反应中的反应性
A mononuclear manganese(iii)-hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions.
作者信息
Sankaralingam Muniyandi, Lee Yong-Min, Jeon So Hyun, Seo Mi Sook, Cho Kyung-Bin, Nam Wonwoo
机构信息
Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea.
出版信息
Chem Commun (Camb). 2018 Jan 31;54(10):1209-1212. doi: 10.1039/c7cc09492b.
PMID:29335701
Abstract
We report the synthesis of manganese(iii)-peroxo (Mn(O)) and manganese(iii)-hydroperoxo (Mn(OH)) complexes by activating dioxygen (O) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.
摘要
我们报道了通过活化双氧（O₂）合成锰（Ⅲ）-过氧（Mn（O））和锰（Ⅲ）-氢过氧（Mn（OOH））配合物，以及锰（Ⅲ）-氢过氧配合物在亲电和亲核反应中的两性反应活性。
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