一种含有5-(嘧啶-5-基)间苯二甲酸的金属杯芳烃配位纳米管。
A metal-calixarene coordination nanotube with 5-(pyrimidin-5-yl)isophthalic acid.
作者信息
Hang Xinxin, Liu Bing, Wang Shentang, Liu Yunling, Liao Wuping
机构信息
State Key Laboratory of Rare Earth Resource Utilization, ERC for the Separation and Purification of REs and Thorium, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.
出版信息
Dalton Trans. 2018 Feb 6;47(6):1782-1785. doi: 10.1039/c7dt04838f.
A metal-organic nanotube (MONT) was assembled by bridging the truncated metal-calixarene octahedra with coordinating water molecules. Remarkably, the tubular compound exhibited a much higher sorption capacity for CH and CH than for CH, and hence represents a promising material for separating these gases. The addition of a little NiSO into the reaction system led to the formation of a 2D metal-calixarene network.
通过用配位水分子连接截短的金属杯芳烃八面体组装了一种金属有机纳米管（MONT）。值得注意的是，该管状化合物对CH₄和C₂H₆的吸附容量比对CH₂的吸附容量高得多，因此是分离这些气体的一种有前景的材料。向反应体系中加入少量NiSO₄导致形成二维金属杯芳烃网络。
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