铜催化的不饱和酮腙的烯烃与胺的二胺化反应。
Copper-Catalyzed Diamination of Alkenes of Unsaturated Ketohydrazones with Amines.
机构信息
Key Laboratory of Medicinal Chemistry, and Molecular Diagnosis of the Ministry of Education, College of Chemistry & Environmental Science, HeBei University , 180 Wusi Donglu, Baoding 071002, P. R. China.
出版信息
Org Lett. 2018 Feb 2;20(3):510-513. doi: 10.1021/acs.orglett.7b03401. Epub 2018 Jan 22.
PMID:29355325
Abstract
A convenient copper-catalyzed intra-/intermolecular diamination of β,γ-unsaturated hydrazones has been developed with simple amines as external amine sources. The protocol enables efficient access to various nitrogen-containing pyrazolines under mild reaction conditions.
摘要
一种方便的铜催化β,γ-不饱和腙的内/分子间二胺化反应已经被开发出来，使用简单的胺作为外部胺源。该方案在温和的反应条件下能够有效地获得各种含氮吡唑啉。
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