异双金属铱 - 铝和铑 - 铝配合物的合成与表征
Synthesis and Characterization of Heterobimetallic Iridium-Aluminum and Rhodium-Aluminum Complexes.
作者信息
Brewster Timothy P, Nguyen Tan H, Li Zhongjing, Eckenhoff William T, Schley Nathan D, DeYonker Nathan J
机构信息
Department of Chemistry, The University of Memphis , 3744 Walker Avenue, Smith Chemistry Building, Memphis, Tennessee 38152, United States.
Department of Chemistry, Rhodes College , 2000 N. Parkway, Memphis, Tennessee 38112, United States.
出版信息
Inorg Chem. 2018 Feb 5;57(3):1148-1157. doi: 10.1021/acs.inorgchem.7b02601. Epub 2018 Jan 22.
We demonstrate the synthesis and characterization of a new class of late-transition-metal-aluminum heterobimetallic complexes via a novel synthetic pathway. Complexes of this type are exceedingly rare. Joint experimental and theoretical data sheds light on the electronic effect of ligands containing aluminum moieties on late-transition-metal complexes.
我们通过一种新颖的合成途径展示了一类新型后过渡金属-铝异双金属配合物的合成与表征。这类配合物极为罕见。联合实验和理论数据揭示了含铝部分的配体对后过渡金属配合物的电子效应。
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