用于硫化氢（HS）阴离子的模块化三脚架受体。
Modular tripodal receptors for the hydrosulfide (HS) anion.
作者信息
Lau Nathanael, Zakharov Lev N, Pluth Michael D
机构信息
Materials Science Institute, Institute of Molecular Biology, Department of Chemistry and Biochemistry, University of Oregon, Eugene, OR 97403, USA.
出版信息
Chem Commun (Camb). 2018 Mar 1;54(19):2337-2340. doi: 10.1039/c7cc09405a.
PMID:29367977
Abstract
Hydrogen sulfide (HS) is an endogenously-produced gasotransmitter and is predominantly speciated as HS at physiological pH. Despite this importance, reversible binding of HS to synthetic receptors remains rare and confined to highly-engineered receptor systems. Here we demonstrate the generality of reversible HS binding in a family of tren-based receptors.
摘要
硫化氢（HS）是一种内源性产生的气体信号分子，在生理pH条件下主要以HS形式存在。尽管其具有重要性，但HS与合成受体的可逆结合仍然很少见，并且局限于高度工程化的受体系统。在此，我们证明了基于三联吡啶的受体家族中HS可逆结合的普遍性。
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