Cáceres Tanya, Venkateswarlu Kadiyala
CERAR, Centre for Environmental Risk Assessment and Remediation, University of South Australia, Mawson Lakes Boulevard, Mawson Lakes, SA, 5095, Australia.
TC Environmental Consultancy, Av. Los Incas N10, Ambato, Ecuador.
Environ Monit Assess. 2018 Feb 2;190(3):109. doi: 10.1007/s10661-018-6493-x.
Although fenamiphos is widely used as an insecticide and nematicide in bowling greens and agriculture, information on its sorption in tropical soils is limited. In this study, mobility, sorption, and desorption dynamics of C-fenamiphos in three contrasting Brazilian soils were examined both in batch and column experiments. Fenamiphos sorption coefficients (K ) were 2.33, 3.86, and 3.9 L kg for the three soils tested. The insecticide exhibited linear adsorption isotherms in all the three soils, and desorption was in a range of 30-40% during a 72-h period. With its low mobility, fenamiphos did not percolate through the soil profile even after 48 h. However, there is a risk of leaching to water bodies due to runoff because of its high solubility in water. In view of the fact that fenamiphos and its oxidation products are highly toxic to aquatic invertebrates and could affect the soil microbial activities even at low concentrations, the present information is of great importance in risk assessment of fenamiphos in the environment.
尽管苯线磷在保龄球场和农业中被广泛用作杀虫剂和杀线虫剂,但关于其在热带土壤中吸附的信息有限。在本研究中,通过批次实验和柱实验研究了三种不同的巴西土壤中C-苯线磷的迁移性、吸附和解吸动力学。所测试的三种土壤的苯线磷吸附系数(K )分别为2.33、3.86和3.9 L kg。该杀虫剂在所有三种土壤中均表现出线性吸附等温线,并且在72小时内解吸率在30 - 40%范围内。由于其迁移性低,即使在48小时后苯线磷也未渗透过土壤剖面。然而,由于其在水中的高溶解度,存在因径流而淋溶到水体的风险。鉴于苯线磷及其氧化产物对水生无脊椎动物具有高毒性,并且即使在低浓度下也可能影响土壤微生物活性,目前的信息对于环境中苯线磷的风险评估非常重要。