NUS Environmental Research Institute, National University of Singapore, 5A Engineering Drive 1, T-Lab Building, Singapore 117411, Singapore.
Department of Civil and Environmental Engineering, Stanford University, CA 94305, USA.
Water Res. 2018 Apr 15;133:182-207. doi: 10.1016/j.watres.2017.12.029. Epub 2017 Dec 28.
Emerging contaminants, such as antibiotics, pharmaceuticals, personal care products, hormones, and artificial sweeteners, are recognized as new classes of water contaminants due to their proven or potential adverse effects on aquatic ecosystems and human health. This review provides comprehensive data on the occurrence of 60 emerging contaminants (ECs) in influent, treated effluent, sludge, and biosolids in wastewater treatment plants (WWTPs). In particular, data on the occurrence of ECs in the influents and effluents of WWTPs are systematically summarized and categorized according to geographical regions (Asia, Europe, and North America). The occurrence patterns of ECs in raw influent and treated effluents of WWTPs between geographical regions were compared and evaluated. Concentrations of most ECs in raw influent in Asian region tend to be higher than those in European and North American countries. Many antibiotics were detected in the influents and effluents of WWTPs at concentrations close to or exceeding the predicted no-effect concentrations (PNECs) for resistance selection. The efficacy of EC removal by sorption and biodegradation during wastewater treatment processes are discussed in light of kinetics and parameters, such as sorption coefficients (K) and biodegradation constants (k), and physicochemical properties (i.e. log K and pK). Commonly used sampling and monitoring strategies are critically reviewed. Analytical research needs are identified, and novel investigative approaches for future monitoring studies are proposed.
新兴污染物,如抗生素、药物、个人护理产品、激素和人工甜味剂,由于其对水生生态系统和人类健康的已证实或潜在的不利影响,被认为是新的一类水污染物。本综述提供了关于 60 种新兴污染物(ECs)在废水处理厂(WWTP)中的进水、处理后的出水、污泥和生物固体中出现的数据。特别是,根据地理区域(亚洲、欧洲和北美洲),系统地总结和分类了 ECs 在 WWTP 进水和出水以及污泥和生物固体中的出现数据。比较和评估了不同地理区域 WWTP 中 raw influent 和 treated effluent 中 ECs 的出现模式。亚洲地区 raw influent 中大多数 ECs 的浓度往往高于欧洲和北美国家。许多抗生素在 WWTP 的进水和出水中被检测到,其浓度接近或超过抗药性选择的预测无影响浓度(PNECs)。讨论了在废水处理过程中通过吸附和生物降解去除 EC 的效果,重点讨论了动力学和参数,如吸附系数(K)和生物降解常数(k)以及物理化学性质(即 log K 和 pK)。批判性地审查了常用的采样和监测策略。确定了分析研究的需求,并提出了未来监测研究的新方法。