β-直接连接的卟啉-咕啉杂化化合物的合成及光谱性质
Synthesis and spectroscopic properties of β- directly linked porphyrin-corrole hybrid compounds.
作者信息
Temelli Baris, Kalkan Hilal
机构信息
Hacettepe University, Department of Chemistry, Beytepe Campus, 06800, Ankara, Turkey.
出版信息
Beilstein J Org Chem. 2018 Jan 22;14:187-193. doi: 10.3762/bjoc.14.13. eCollection 2018.
Abstract
The preparation of β- directly linked porphyrin-corrole hybrids was realized for the first time via an InCl-catalyzed condensation reaction of 2-formyl-5,10,15,20-tetraphenylporphyrins with -substituted dipyrromethanes. Hybrid compounds have been characterized by H NMR, C NMR, 2D NMR, UV-vis absorption and fluorescence spectroscopy.
摘要
首次通过三氯化铟催化的2-甲酰基-5,10,15,20-四苯基卟啉与β-取代二吡咯甲烷的缩合反应实现了β-直接连接的卟啉-咕啉杂化物的制备。杂化化合物已通过氢核磁共振、碳核磁共振、二维核磁共振、紫外可见吸收光谱和荧光光谱进行了表征。
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