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β-直接连接的卟啉-咕啉杂化化合物的合成及光谱性质

Synthesis and spectroscopic properties of β- directly linked porphyrin-corrole hybrid compounds.

作者信息

Temelli Baris, Kalkan Hilal

机构信息

Hacettepe University, Department of Chemistry, Beytepe Campus, 06800, Ankara, Turkey.

出版信息

Beilstein J Org Chem. 2018 Jan 22;14:187-193. doi: 10.3762/bjoc.14.13. eCollection 2018.

DOI:10.3762/bjoc.14.13
PMID:29441141
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5789387/
Abstract

The preparation of β- directly linked porphyrin-corrole hybrids was realized for the first time via an InCl-catalyzed condensation reaction of 2-formyl-5,10,15,20-tetraphenylporphyrins with -substituted dipyrromethanes. Hybrid compounds have been characterized by H NMR, C NMR, 2D NMR, UV-vis absorption and fluorescence spectroscopy.

摘要

首次通过三氯化铟催化的2-甲酰基-5,10,15,20-四苯基卟啉与β-取代二吡咯甲烷的缩合反应实现了β-直接连接的卟啉-咕啉杂化物的制备。杂化化合物已通过氢核磁共振、碳核磁共振、二维核磁共振、紫外可见吸收光谱和荧光光谱进行了表征。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e33c/5789387/224e8d82a38b/Beilstein_J_Org_Chem-14-187-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e33c/5789387/60a105df2ecb/Beilstein_J_Org_Chem-14-187-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e33c/5789387/87b82c620dc4/Beilstein_J_Org_Chem-14-187-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e33c/5789387/65552b713d1e/Beilstein_J_Org_Chem-14-187-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e33c/5789387/224e8d82a38b/Beilstein_J_Org_Chem-14-187-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e33c/5789387/60a105df2ecb/Beilstein_J_Org_Chem-14-187-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e33c/5789387/87b82c620dc4/Beilstein_J_Org_Chem-14-187-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e33c/5789387/65552b713d1e/Beilstein_J_Org_Chem-14-187-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e33c/5789387/224e8d82a38b/Beilstein_J_Org_Chem-14-187-g002.jpg

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Chem Rev. 2017 Feb 22;117(4):3102-3137. doi: 10.1021/acs.chemrev.6b00434. Epub 2016 Nov 4.
3
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Chemistry. 2016 Jan 22;22(4):1301-12. doi: 10.1002/chem.201503490. Epub 2015 Nov 30.
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Dalton Trans. 2015 Aug 14;44(30):13473-9. doi: 10.1039/c5dt01730k.
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