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荧光杂孔共价有机框架的构建及其在高选择性和高灵敏度光谱和可视化检测三硝基苯酚中的应用。

The construction of fluorescent heteropore covalent organic frameworks and their applications in spectroscopic and visual detection of trinitrophenol with high selectivity and sensitivity.

作者信息

Zhu Ming-Wei, Xu Shun-Qi, Wang Xiao-Zhong, Chen Yingqi, Dai Liyan, Zhao Xin

机构信息

College of Chemical and Biological Engineering, Zhejiang University, 38# Zheda Road, Xihu District, Hangzhou 310058, P. R. China.

出版信息

Chem Commun (Camb). 2018 Feb 27;54(18):2308-2311. doi: 10.1039/c8cc00203g.

Abstract

Two fluorescent covalent organic frameworks (COFs) which bear two kinds of pores with different sizes and shapes have been synthesized. The heteropore COFs exhibit spectroscopic and color changes to 2,4,6-trinitrophenol (TNP) with extremely high selectivity and sensitivity, which makes them excellent macroscopic chemosensors for the selective detection of TNP.

摘要

已经合成了两种具有不同尺寸和形状的孔的荧光共价有机框架(COF)。这种异质孔COF对2,4,6-三硝基苯酚(TNP)表现出光谱和颜色变化,具有极高的选择性和灵敏度,这使其成为用于选择性检测TNP的优异宏观化学传感器。

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