用于π-芳香性和反芳香性分析的非解剖核独立化学位移分析
Dissected Nucleus-Independent Chemical Shift Analysis of π-Aromaticity and Antiaromaticity.
作者信息
Schleyer Paul von Ragué, Manoharan Mariappan, Wang Zhi-Xiang, Kiran Boggavarapu, Jiao Haijun, Puchta Ralph, van Eikema Hommes Nicolaas J R
机构信息
Department of Chemistry, Computational Chemistry Annex, University of Georgia, Athens, Georgia 30602, and Computational Chemistry Center and Institute of Organic Chemistry, University of Erlangen-Nuremberg, Henkestrasse 42, D-91054 Erlangen, Germany.
出版信息
Org Lett. 2001 Aug 9;3(16):2465-2468. doi: 10.1021/ol016217v.
Analysis of the basic π-aromatic (benzene) and antiaromatic (cyclobutadiene) systems by dissected nucleus-independent chemical shifts (NICS) shows the contrasting diatropic and paratropic effects, but also reveals subtleties and unexpected details.
通过剖析的核独立化学位移（NICS）对基本的π-芳香性（苯）和反芳香性（环丁二烯）体系进行分析，结果显示出相反的抗磁和顺磁效应，但同时也揭示了一些微妙之处和意想不到的细节。
Zotero 插件