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Palladium Nanoparticles for the Deuteration and Tritiation of Benzylic Positions on Complex Molecules.
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C-H Activation and Hydrogen Isotope Exchange of Aryl Carbamates Using Iridium(I) Complexes Bearing Chelating NHC-Phosphine Ligands.
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Hydrogen Isotope Labeling of Pharmaceuticals Via Dual Hydrogen Isotope Exchange Pathways Using CdS Quantum Dot Photocatalyst.
J Am Chem Soc. 2024 Dec 11;146(49):34141-34151. doi: 10.1021/jacs.4c13857. Epub 2024 Nov 23.
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Selective monodeuteration enabled by bisphosphonium catalyzed ring opening processes.
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Electrochemical hydrogen isotope exchange of amines controlled by alternating current frequency.
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Precision Deuteration Using Cu-Catalyzed Transfer Hydrodeuteration to Access Small Molecules Deuterated at the Benzylic Position.
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Visible-light mediated catalytic asymmetric radical deuteration at non-benzylic positions.
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Site-Selective Silver-Catalyzed C-H Bond Deuteration of Five-Membered Aromatic Heterocycles and Pharmaceuticals.
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Catalytic asymmetric synthesis of enantioenriched α-deuterated pyrrolidine derivatives.
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1
Formation of Aryl- and Benzylboronate Esters by Rhodium-Catalyzed C-H Bond Functionalization with Pinacolborane.
Angew Chem Int Ed Engl. 2001 Jun 1;40(11):2168-2171. doi: 10.1002/1521-3773(20010601)40:11<2168::AID-ANIE2168>3.0.CO;2-0.
2
The Essential Role of Bond Energetics in C-H Activation/Functionalization.
Chem Rev. 2017 Jul 12;117(13):8622-8648. doi: 10.1021/acs.chemrev.6b00664. Epub 2017 Mar 10.
3
Benzyltriboronates: Building Blocks for Diastereoselective Carbon-Carbon Bond Formation.
J Am Chem Soc. 2017 Feb 22;139(7):2589-2592. doi: 10.1021/jacs.6b12896. Epub 2017 Feb 13.
5
Stereoretentive Deuteration of α-Chiral Amines with DO.
J Am Chem Soc. 2016 Oct 19;138(41):13489-13492. doi: 10.1021/jacs.6b07879. Epub 2016 Oct 6.
6
Cobalt-Catalyzed C(sp(2))-H Borylation: Mechanistic Insights Inspire Catalyst Design.
J Am Chem Soc. 2016 Aug 24;138(33):10645-53. doi: 10.1021/jacs.6b06144. Epub 2016 Aug 15.
7
Iron-catalysed tritiation of pharmaceuticals.
Nature. 2016 Jan 14;529(7585):195-9. doi: 10.1038/nature16464.
8
Cobalt-Catalyzed Benzylic Borylation: Enabling Polyborylation and Functionalization of Remote, Unactivated C(sp(3))-H Bonds.
J Am Chem Soc. 2016 Jan 27;138(3):766-9. doi: 10.1021/jacs.5b12249. Epub 2016 Jan 12.
9
Silver(I)-Catalyzed Diastereoselective Synthesis of anti-1,2-Hydroxyboronates.
Angew Chem Int Ed Engl. 2015 Nov 16;54(47):14141-5. doi: 10.1002/anie.201507171. Epub 2015 Sep 25.
10
Enantiospecific C-H Activation Using Ruthenium Nanocatalysts.
Angew Chem Int Ed Engl. 2015 Sep 1;54(36):10474-7. doi: 10.1002/anie.201504554.

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