Intasa-Ard Soontaree Grace, Imwiset Kamonnart Jaa, Bureekaew Sareeya, Ogawa Makoto
School of Molecular Science and Engineering, Vidyasirimedhi Institute of Science and Technology, 555 Moo 1 Payupnai, Wangchan, Rayong 21210, Thailand.
Dalton Trans. 2018 Feb 27;47(9):2896-2916. doi: 10.1039/c7dt03736h.
Due to increasing interest in the development of advanced nanomaterials from nanosheets as building blocks, methods for the preparation of nanosheet materials and their hybrids have been studied carefully and extensively. In this review, studies of mechanochemical methods (solid-solid reactions under ambient conditions or solvent-free synthesis) for the preparation of intercalation compounds are summarized. Mechanochemical reactions without using solvent have operational advantages, such as their environmentally benign nature and the fact that separating and drying the products is not necessary. In addition to their advantages from green chemistry viewpoints, solid-state reactions have potential for the preparation of novel intercalation compounds which are not accessible by conventional solution-based methods.
由于人们对以纳米片为构建单元开发先进纳米材料的兴趣日益浓厚，制备纳米片材料及其杂化物的方法已得到仔细且广泛的研究。在本综述中，总结了用于制备插层化合物的机械化学方法（环境条件下的固-固反应或无溶剂合成）的研究。不使用溶剂的机械化学反应具有操作优势，例如其环境友好性以及无需分离和干燥产物这一事实。除了从绿色化学角度来看具有优势外，固态反应在制备传统溶液法无法获得的新型插层化合物方面具有潜力。
