Liu Heng, Kulbitski Kseniya, Tamm Matthias, Eisen Moris S
Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa City, 32000, Israel.
Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106, Braunschweig, Germany.
Chemistry. 2018 Apr 17;24(22):5738-5742. doi: 10.1002/chem.201705987. Epub 2018 Mar 23.
The organoactinide-catalyzed monohydroboration of carbodiimides is reported herein. The catalytic reactions proceed under very mild conditions in a highly atom-efficient and highly selective fashion to afford the corresponding monohydroborated N-borylformamidine products in high yields. A plausible mechanism is proposed based on stoichiometric and kinetic studies.
本文报道了有机锕系元素催化的碳二亚胺单硼氢化反应。催化反应在非常温和的条件下以高原子经济性和高选择性的方式进行，以高收率得到相应的单硼氢化N-硼基甲脒产物。基于化学计量和动力学研究提出了一个合理的反应机理。
