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工程 DNA 分子桥在金属电极之间用于高性能分子晶体管:一种环境依赖的方法。

Engineering DNA Molecule Bridge between Metal Electrodes for High-Performance Molecular Transistor: An Environmental Dependent Approach.

机构信息

Department of Physics, Faculty of Science , Urmia University of Technology , Urmia , Iran.

出版信息

J Phys Chem B. 2018 Mar 8;122(9):2487-2494. doi: 10.1021/acs.jpcb.7b10034. Epub 2018 Feb 28.

Abstract

Molecule-based transistors have attracted much attention due to their exclusive properties. Creation of a molecular transistor as well as engineering its structure have become one of the greatest aims of scientists. We have focused on the environmental dependent behavior of a DNA-templated transistor. Using the statistical distribution of the energy levels, we were able to distinguish the delocalized states of charge carriers and the transition between the localized and delocalized behaviors. On the other hand, we can determine the stability conditions of our quantum dynamical system. The results are verified by the inverse participation ratio method. Therefore, the most appropriate parameters for designing the DNA transistor are chosen. The DNA sequence is an important factor for its transport properties, but the results have shown that in the presence of the bath, the bath parameters are important, too. As is shown, it is possible that via the adjustment of bath parameters, one can design a conductivity channel for all nucleotide contents. Thus, one can engineer a DNA based transistor simply through the setting of only one parameter.

摘要

基于分子的晶体管由于其独特的性质而引起了广泛关注。创建分子晶体管并对其结构进行工程设计已成为科学家们的最大目标之一。我们专注于 DNA 模板晶体管的环境相关行为。通过能级的统计分布,我们能够区分电荷载流子的离域态和局域态与离域态之间的转变。另一方面,我们可以确定我们量子动力学系统的稳定性条件。结果通过逆参与比方法得到验证。因此,选择了最适合设计 DNA 晶体管的参数。DNA 序列是其传输特性的重要因素,但结果表明,在存在浴的情况下,浴参数也很重要。事实证明,通过调整浴参数,可以为所有核苷酸含量设计一个导电通道。因此,通过仅设置一个参数,就可以简单地设计基于 DNA 的晶体管。

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