Gnaim Samer, Shabat Doron
School of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv 69978, Israel.
Chem Commun (Camb). 2018 Mar 8;54(21):2655-2658. doi: 10.1039/c8cc00521d.
A new signal amplification system with an auto-inductive mode of action and distinct chemiluminescence output was developed. The system is composed of a unique structural motif that combines a chemiexcitation mechanism with a quinone-methide elimination into a signal building block. As demonstrated with a probe designed to detect fluoride, an auto-inductive chemiluminescence signal amplification was obtained through self-immolative disassembly and light emission mechanisms.
开发了一种具有自感应作用模式和独特化学发光输出的新型信号放大系统。该系统由一个独特的结构基序组成，该基序将化学激发机制与醌甲基化物消除结合到一个信号构建模块中。如用一个设计用于检测氟化物的探针所证明的，通过自牺牲拆解和发光机制获得了自感应化学发光信号放大。
