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ZnO-SnO纳米颗粒和活性炭对甲苯在连续流动模式下光催化降解的影响。

The influence of ZnO-SnO nanoparticles and activated carbon on the photocatalytic degradation of toluene using continuous flow mode.

作者信息

Rangkooy Hossein Ali, Tanha Fatemeh, Jaafarzadeh Neamat, Mohammadbeigi Abolfazl

机构信息

Environmental Technologies Research Center, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran.

Department of Occupational Health, Health Faculty, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran.

出版信息

Med Gas Res. 2018 Jan 22;7(4):260-264. doi: 10.4103/2045-9912.222450. eCollection 2017 Oct-Dec.

Abstract

The present study examined the gas-phase photocatalytic degradation of toluene using ZnO-SnO nanocomposite supported on activated carbon in a photocatalytic reactor. Toluene was selected as a model pollutant from volatile organic compounds to determine the pathway of photocatalytic degradation and the factors influencing this degradation. The ZnO-SnO nanocomposite was synthesized through co-precipitation method in a ratio of 2:1 and then supported on activated carbon. The immobilization of ZnO-SnO nanocomposite on activated carbon was determined by the surface area and scanning electron micrograph technique proposed by Brunauer, Emmett, and Teller. The laboratory findings showed that the highest efficiency was 40% for photocatalytic degradation of toluene. The results also indicated that ZnO-SnO nano-oxides immobilization on activated carbon had a synergic effect on photocatalytic degradation of toluene. Use of a hybrid photocatalytic system (ZnO/SnO nano coupled oxide) and application of absorbent (activated carbon) may be efficient and effective technique for refinement of toluene from air flow.

摘要

本研究考察了在光催化反应器中,负载于活性炭上的ZnO-SnO纳米复合材料对甲苯的气相光催化降解。从挥发性有机化合物中选择甲苯作为模型污染物,以确定光催化降解途径及影响该降解的因素。通过共沉淀法以2:1的比例合成ZnO-SnO纳米复合材料,然后负载于活性炭上。采用Brunauer、Emmett和Teller提出的比表面积和扫描电子显微镜技术测定ZnO-SnO纳米复合材料在活性炭上的负载情况。实验室结果表明,甲苯光催化降解的最高效率为40%。结果还表明,ZnO-SnO纳米氧化物负载于活性炭上对甲苯的光催化降解具有协同作用。使用混合光催化系统(ZnO/SnO纳米耦合氧化物)和应用吸附剂(活性炭)可能是从气流中提纯甲苯的高效技术。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0c2e/5806447/67b52f8a62ce/MGR-7-260-g001.jpg

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