Smith Albert A, Testori Emilie, Cadalbert Riccardo, Meier Beat H, Ernst Matthias
Physical Chemistry, ETH Zürich, Vladimir-Prelog-Weg 2, 8093, Zurich, Switzerland.
J Biomol NMR. 2018 Mar;70(3):203. doi: 10.1007/s10858-018-0170-9.
In our recent publication (Smith et al., J Biomol NMR 65:171-191, 2016) on the dynamics of HET-s(218-289), we reported on page 176, that calculation of solid-state NMR R rate constants using analytical equations based on Redfield theory (Kurbanov et al., J Chem Phys 135:184104:184101-184109, 2011) failed when the correlation time of motion becomes too long.
在我们最近发表的关于HET-s(218 - 289)动力学的论文(Smith等人,《生物分子核磁共振杂志》65:171 - 191,2016年)中,我们在第176页报道,当运动的相关时间变得过长时,使用基于Redfield理论的解析方程(Kurbanov等人,《化学物理杂志》135:184104:184101 - 184109,2011年)来计算固态核磁共振R速率常数会失败。