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纳米探索之旅:在界面处驱动纳米车/分子机器

Nano Trek Beyond: Driving Nanocars/Molecular Machines at Interfaces.

机构信息

World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan.

Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba, 277-8561, Japan.

出版信息

Chem Asian J. 2018 May 18;13(10):1266-1278. doi: 10.1002/asia.201800225. Epub 2018 Apr 18.

Abstract

In 2016, the Nobel Prize in Chemistry was awarded for pioneering work on molecular machines. Half a year later, in Toulouse, the first molecular car race, a "nanocar race", was held by using the tip of a scanning tunneling microscope as an electrical remote control. In this Focus Review, we discuss the current state-of-the-art in research on molecular machines at interfaces. In the first section, we briefly explain the science behind the nanocar race, followed by a selection of recent examples of controlling molecules on surfaces. Finally, motion synchronization and the functions of molecular machines at liquid interfaces are discussed. This new concept of molecular tuning at interfaces is also introduced as a method for the continuous modification and optimization of molecular structure for target functions.

摘要

2016 年,诺贝尔化学奖授予了在分子机器方面的开创性工作。半年后,在图卢兹,使用扫描隧道显微镜的尖端作为电气远程控制,举办了第一届分子汽车比赛,即“纳米汽车比赛”。在本期专题评论中,我们讨论了界面上分子机器研究的最新进展。在第一节中,我们简要解释了纳米汽车比赛背后的科学原理,然后选择了最近在表面控制分子的一些例子。最后,讨论了分子在液体界面上的运动同步和机器的功能。我们还将分子在界面上的这种新的调谐概念引入到连续修改和优化目标功能的分子结构的方法中。

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