通过自由基生成和添加叔丁基氮杂羧酸酯合成腙。
Synthesis of Hydrazines via Radical Generation and Addition of Azocarboxylic tert-Butyl Esters.
机构信息
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry & Materials Science , Northwest University , Xi'an 710069 , P. R. China.
出版信息
Org Lett. 2018 Apr 6;20(7):1910-1913. doi: 10.1021/acs.orglett.8b00448. Epub 2018 Mar 9.
PMID:29522348
Abstract
A new chemistry of azo compounds that is a radical generation and addition in situ of azocarboxylic tert-butyl esters to synthesize hydrazines has been described. The protocol provides a novel strategy for the synthesis of various hydrazines. The advantages of the transformation include broad substrate scope, benign conditions, and convenient operation.
摘要
已经描述了一种新的偶氮化合物化学，即通过自由基引发和原位加成叔丁基偶氮羧酸酯合成腙。该方案为各种腙的合成提供了一种新的策略。该转化的优点包括广泛的底物范围、温和的条件和方便的操作。
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