用于高效气体存储和分离的多孔配位聚合物中的统一介孔和密集铜位点
Unified meso-pores and dense Cu sites in porous coordination polymers for highly efficient gas storage and separation.
作者信息
Lyu Hongliang, Zhang Qiang, Wang Yang, Duan Jingui
机构信息
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China.
出版信息
Dalton Trans. 2018 Mar 26;47(13):4424-4427. doi: 10.1039/c8dt00512e.
PMID:29532842
Abstract
Unified meso-pores and dense open metal sites (OMS) in porous coordination polymers (PCPs) allow highly promising H2 and C2-hydrocarbon storage, as well as rapid and efficient C2H2/4 enrichment from CO2 mixtures. The positive function of the OMS, associated with guest thermodynamics, was well revealed by in situ infrared (IR) spectroscopy study.
摘要
多孔配位聚合物（PCP）中统一的中孔和密集的开放金属位点（OMS）使得其在氢气和C2烃储存方面极具潜力，同时也能从二氧化碳混合物中快速高效地富集乙炔/乙烯。通过原位红外（IR）光谱研究，与客体热力学相关的开放金属位点的积极作用得到了很好的揭示。
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