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具有三重周期性极小曲面及相关几何结构的材料概述:从生物结构到自组装体系。

An Overview of Materials with Triply Periodic Minimal Surfaces and Related Geometry: From Biological Structures to Self-Assembled Systems.

机构信息

School of Chemical Science and Engineering, Tongji University, 1239 Siping Road, Shanghai, 200092, P. R. China.

出版信息

Adv Mater. 2018 Apr;30(17):e1705708. doi: 10.1002/adma.201705708. Epub 2018 Mar 15.

Abstract

Triply periodic minimal surface structures and related geometries are widely identified in many natural systems, such as biological membranes and biophotonic structures in butterfly-wing scales. Inspired by their marvelous and highly symmetrical structures and optimized physical properties, these structures have sparked immense interest for creating novel materials by extracting the design from nature. Significant progress has been made to understand these biological structures and fabricate artificial materials by top-down and bottom-up approaches for numerous applications in chemistry and materials science. Herein, research achievements, including theoretical and experimental discoveries, in both biological systems and the artificial synthesis of materials with triply periodic minimal surface structures and related materials are summarized. Recent developments in self-assembled lyotropic liquid crystal phases, block copolymer systems, and their inorganic replicas are discussed in detail.

摘要

三维周期极小曲面结构及其相关几何形状在许多自然系统中广泛存在,如生物膜和蝴蝶翅膀鳞片中的生物光子结构。受其奇妙而高度对称的结构和优化的物理性能的启发,这些结构激发了人们通过从自然界中提取设计来创造新型材料的极大兴趣。通过自上而下和自下而上的方法,已经取得了重大进展,以了解这些生物结构并制造用于化学和材料科学的众多应用的人工材料。本文总结了在生物体系和具有三重周期性极小曲面结构和相关材料的人工合成材料的理论和实验发现方面的研究成果。详细讨论了自组装溶致液晶相、嵌段共聚物体系及其无机复制品的最新进展。

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