从滇南乌头根中分离得到的四种新的C-二萜生物碱。
Four new C-diterpenoid alkaloids from the roots of Aconitum ouvrardianum.
作者信息
Liu Wang-Yan, He Dan, Zhao Da-Ke, Chen Yan-Ping, Shen Yong
机构信息
a College of Agriculture and Biotechnology , Yunnan Agricultural University , Kunming 650201 , China.
b Laboratory of Ecology and Evolutionary Biology, State Key Laboratory for Conservation and Utilization of Bio- Resources , Yunnan University , Kunming 650201 , China.
出版信息
J Asian Nat Prod Res. 2019 Jan;21(1):9-16. doi: 10.1080/10286020.2018.1451520. Epub 2018 Mar 23.
Four new C-diterpenoid alkaloids, 3-dehydroxyl-lipoindaconitine (1), 8-dehydroxyl-bikhaconine (2), 19R-acetonyl-talatisamine (3), and 16-hydroxyl-vilmorisine (4), were isolated from the roots of Aconitum ouvrardianum. Their structures were elucidated by spectral analyses, including ESI-MS, HR-ESI-MS, IR, UV, 1D and 2D NMR.
从滇南乌头的根部分离得到了4个新的C-二萜生物碱，分别为3-去羟基-脂乌头碱（1）、8-去羟基-滇乌碱（2）、19R-丙酮基-塔拉胺（3）和16-羟基-紫乌碱（4）。通过光谱分析，包括电喷雾电离质谱（ESI-MS）、高分辨电喷雾电离质谱（HR-ESI-MS）、红外光谱（IR）、紫外光谱（UV）、一维和二维核磁共振谱（1D和2D NMR）对它们的结构进行了鉴定。
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