Instrument Technology Research Center, Natl. Applied Research Laboratories, Hsinchu, 30076, Taiwan.
Dept. of Materials Science and Engineering, Natl. Tsing Hua Univ., Hsinchu, 300, Taiwan.
J Food Sci. 2018 Apr;83(4):975-983. doi: 10.1111/1750-3841.14060. Epub 2018 Mar 25.
Coffee is a stimulant, psychoactive, popular daily beverage, and its caffeine affects human physiological health and behavior. These important issues prompted us to study caffeine extraction from both the raw and roasted coffee beans of 3 types at different temperatures. A hemispheric model is developed to simulate the extraction process of the caffeine from the coffee beans of hemisphere is proposed. The experimental data are in good agreement with the predicted model. The effective diffusivities of caffeine in both the raw and roasted beans increase with temperature in all 3 types. An incubation period, decreasing with increasing temperature, is observed in all samples studied. Caffeine extraction in roasted beans is more rapid than that for the raw beans and the time difference is significant at low temperatures. In both the raw and roasted samples, caffeine diffusion in the raw beans and the incubation behavior are thermally activated processes. Single activation energies are obtained for diffusion within the extraction temperature range for all beans tested with the exception of one type of the coffee beans, Mandheling, which exhibits 2 activation energies in raw samples. The surface energies of the epidermis of the raw beans and roasted beans obtained from the contact angle measurements are used to interpret the difference of incubation periods.
This study has a potential application to the decaffeinated coffee industry.Caffeine affects human physiological health and behavior so that caffeine extraction from coffee beans of different types at different temperatures is important for product refining and customers.
咖啡是一种兴奋剂、具有精神活性,是一种受欢迎的日常饮品,其咖啡因会影响人体的生理健康和行为。这些重要问题促使我们研究从 3 种不同类型的生豆和烘焙豆中在不同温度下提取咖啡因。提出了一种半球模型来模拟从半球形咖啡豆中提取咖啡因的过程。实验数据与预测模型吻合良好。在所有 3 种咖啡豆中,咖啡因在生豆和烘焙豆中的有效扩散系数均随温度升高而增加。在所有研究的样品中,都观察到随着温度升高而减少的潜伏期。烘焙豆中的咖啡因提取比生豆更快,并且在低温下时间差异明显。在生豆和烘焙豆中,咖啡因在生豆中的扩散和潜伏期行为都是热激活过程。除了一种咖啡豆(曼特宁)外,对于所有测试的咖啡豆,在提取温度范围内,都可以获得单个扩散激活能,而曼特宁豆的生豆样本则表现出 2 个激活能。通过接触角测量获得的生豆和烘焙豆表皮的表面能用于解释潜伏期差异。
本研究对脱咖啡因咖啡行业具有潜在应用价值。咖啡因会影响人体的生理健康和行为,因此从不同类型的咖啡豆在不同温度下提取咖啡因对于产品精炼和客户非常重要。