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具有长有效光载流子寿命的喷墨可打印光活性全无机钙钛矿薄膜。

Inkjet printable-photoactive all inorganic perovskite films with long effective photocarrier lifetimes.

作者信息

Ilie C C, Guzman F, Swanson B L, Evans I R, Costa P S, Teeter J D, Shekhirev M, Benker N, Sikich S, Enders A, Dowben P A, Sinitskii A, Yost A J

机构信息

Department of Physics, State University of New York-Oswego, Oswego, NY 13126-3599, United States of America.

出版信息

J Phys Condens Matter. 2018 May 10;30(18):18LT02. doi: 10.1088/1361-648X/aab986. Epub 2018 Mar 26.

Abstract

Photoactive perovskite quantum dot films, deposited via an inkjet printer, have been characterized by x-ray diffraction and x-ray photoelectron spectroscopy. The crystal structure and bonding environment are consistent with CsPbBr perovskite quantum dots. The current-voltage (I-V) and capacitance-voltage (C-V) transport measurements indicate that the photo-carrier drift lifetime can exceed 1 ms for some printed perovskite films. This far exceeds the dark drift carrier lifetime, which is below 50 ns. The printed films show a photocarrier density 10 greater than the dark carrier density, making these printed films ideal candidates for application in photodetectors. The successful printing of photoactive-perovskite quantum dot films of CsPbBr, indicates that the rapid prototyping of various perovskite inks and multilayers is realizable.

摘要

通过喷墨打印机沉积的光活性钙钛矿量子点薄膜,已通过X射线衍射和X射线光电子能谱进行了表征。晶体结构和键合环境与CsPbBr钙钛矿量子点一致。电流-电压(I-V)和电容-电压(C-V)传输测量表明,对于某些印刷的钙钛矿薄膜,光载流子漂移寿命可以超过1毫秒。这远远超过了暗漂移载流子寿命,暗漂移载流子寿命低于50纳秒。印刷薄膜显示出的光载流子密度比暗载流子密度大10倍,这使得这些印刷薄膜成为光探测器应用的理想候选材料。CsPbBr光活性钙钛矿量子点薄膜的成功印刷,表明各种钙钛矿墨水和多层膜的快速原型制作是可行的。

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