芳基偶氮吡唑光开关在水溶液中的取代基效应、光物理性质和主客体化学。
Arylazopyrazole Photoswitches in Aqueous Solution: Substituent Effects, Photophysical Properties, and Host-Guest Chemistry.
机构信息
Organic Chemistry Institute and Center for Soft Nanoscience, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, 48149, Münster, Germany.
Institute for Solid State Theory and Center for Multiscale Theory, & Computation, Westfälische Wilhelms-Universität Münster, Wilhelm-Klemm Str. 10, 48149, Münster, Germany.
出版信息
Chemistry. 2018 Jun 18;24(34):8639-8647. doi: 10.1002/chem.201800587. Epub 2018 May 24.
Getting the green light! Substituted arylazopyrazoles (AAPs) have been investigated as supramolecular photoswitches in aqueous solution. Selective photostationary states (PSSs) and improved binding affinities to β-cyclodextrin have been determined. The experimental findings are supported by results from DFT calculations.
获得批准！取代芳基偶氮吡唑（AAPs）已被研究为水溶液中的超分子光开关。确定了选择性光稳定态（PSSs）和对β-环糊精的结合亲和力的提高。实验结果得到了 DFT 计算结果的支持。
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