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新型荧光传感器对食品中没食子酸丙酯的高特异性和高灵敏度测定。

Highly specific and sensitive determination of propyl gallate in food by a novel fluorescence sensor.

机构信息

College of Food Science and Engineering, Northwest A&F University, Yangling 712100, Shaanxi, China.

College of Food Science and Engineering, Northwest A&F University, Yangling 712100, Shaanxi, China.

出版信息

Food Chem. 2018 Aug 1;256:45-52. doi: 10.1016/j.foodchem.2018.02.108. Epub 2018 Feb 21.

Abstract

Propyl gallate (PG), one of the most widely used synthetic phenolic antioxidants in edible oil, cookies and fried food, has received extensive concern due to its possible toxic effects on human health. Herein, a novel fluorescence analytical method is firstly proposed to sensitively and selectively determine propyl gallate (PG) by utilizing the unique fluorescence quenching property of organic molybdate complex (OMC) formed by the specific reaction between MoO and PG to g-CN nanosheets. Under the optimum conditions, the developed fluorescence sensor allows highly sensitive detection of PG in a wide range from 0.5 to 200 μg mL with a detection limit of 0.11 μg mL, and possesses excellent specificity and good recoveries. All the analytical results indicate the present method provides an effective approach for rapid detection of PG in common products, which is beneficial for monitoring and reducing the risk of overuse of PG.

摘要

没食子酸丙酯(PG)是食用油、饼干和油炸食品中应用最广泛的合成酚类抗氧化剂之一,由于其对人类健康可能产生的毒性作用而受到广泛关注。在此,首次提出了一种新的荧光分析方法,通过利用 MoO 与 PG 之间的特定反应形成的有机钼酸盐配合物(OMC)的独特荧光猝灭特性,灵敏且选择性地测定没食子酸丙酯(PG)。在最佳条件下,所开发的荧光传感器能够在 0.5 至 200μg/mL 的较宽范围内对 PG 进行高灵敏度检测,检测限为 0.11μg/mL,具有出色的特异性和良好的回收率。所有分析结果表明,该方法为快速检测常见产品中的 PG 提供了一种有效方法,有利于监测和降低 PG 过度使用的风险。

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