Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al chloride.

作者信息

Gu Bin, Sun Chenglin, Fettinger James C, Casey William H, Dikhtiarenko Alla, Gascon Jorge, Koichumanova Kamila, Babu Sai Sankar Gupta Karthick, Jan Heeres Hero, He Songbo

机构信息

Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China.

出版信息

Chem Commun (Camb). 2018 Apr 19;54(33):4148-4151. doi: 10.1039/c8cc01363b.

DOI:10.1039/c8cc01363b

PMID:29623969

Abstract

Herein we present the first example of a glycol-coordinated ε-Keggin Al13 chloride (gl-ε-Al13), which is the first chelated version since discovery of Al13 in 1960. The molecular structure consists of [AlO4Al12(OH)12(OC2H4OH)12]Cl7·H2O units with chelating mono-anionic ethylene glycol units replacing one bridging and one terminal oxygen site.

摘要